Close-up of shiny metallic mineral crystals with reflective surfaces.

A History Of Titanium

Titanium stands as one of the most remarkable metals discovered in modern history, combining extraordinary strength with lightweight properties that have revolutionized industries from aerospace to medicine. Despite being the ninth most abundant element in Earth’s crust, titanium’s journey from an obscure oxide in black sand to an indispensable material in cutting-edge technology spans over two centuries of scientific discovery and industrial innovation. This metal, named after the mighty Titans of Greek mythology, has proven worthy of its mythological namesake through its exceptional resistance to corrosion, biocompatibility with human tissue, and ability to maintain strength at extreme temperatures. Today, titanium shapes our world in ways both visible and hidden, from the aircraft that carry us across continents to the medical implants that restore mobility and save lives.

Be sure to check out all other critical raw materials (CRMs), as well.

A History Of Titanium

The chronicle of titanium encompasses more than 230 years of scientific discovery, technological breakthroughs, and industrial applications. From its initial identification in English beach sands to its current status as an essential material in aerospace, medical, and industrial applications, titanium’s history reflects humanity’s persistent quest to harness nature’s elements for technological advancement. This timeline documents the major milestones in titanium’s evolution from a laboratory curiosity to one of the most strategically important metals of the 21st century.

Chronology

  • 1791 William Gregor, an English clergyman and amateur mineralogist, discovered a new element in black magnetic sand from the Manaccan valley in Cornwall, England, identifying iron oxide and an unknown white metallic oxide he named “manaccanite” [1, 2, 3, 4, 5, 6, 7, 8, 9, 11]
  • 1795 Martin Heinrich Klaproth, a German chemist, independently discovered the same element in Hungarian rutile ore and named it “titanium” after the Titans of Greek mythology [1, 2, 3, 4, 5, 7, 8, 9, 11]
  • 1797 Klaproth confirmed that his titanium and Gregor’s manaccanite were the same element after examining samples from Cornwall [3, 4, 9]
  • 1887 Lars Fredrik Nilson and Otto Pettersson achieved 95% pure titanium through chemical reduction [4, 7]
  • 1896 Henri Moissan produced titanium with 98% purity using an electric furnace, though the product was brittle due to contamination [7]
  • 1906 Matthew A. Hunter at Rensselaer Polytechnic Institute, in cooperation with General Electric Company, first produced pure metallic titanium while searching for lightbulb filament material [11]
  • 1908 Titanium’s high affinity for nitrogen at high temperatures was documented [7]
  • 1910 Matthew A. Hunter developed the Hunter process, producing 99.9% pure titanium by reducing titanium tetrachloride with sodium at 700-800°C [1, 2, 3, 4, 5, 8, 11, 19]
  • 1925 Anton Eduard van Arkel and Jan Hendrik de Boer discovered the iodide process, producing very high purity titanium by decomposing titanium tetraiodide over a hot filament [4, 10, 11]
  • 1932 William J. Kroll produced significant quantities of ductile titanium by combining titanium tetrachloride with calcium [11]
  • 1937 Kroll developed the process for isolating titanium by reduction with magnesium, later known as the Kroll process [14, 16]
  • 1938 Kroll fled Europe at the start of World War II and continued his work in the United States at Union Carbide Company and the U.S. Bureau of Mines [11]
  • 1940 The first report on commercially pure titanium for medicine appeared, showing excellent bone compatibility in animal tests [23, 24]
  • 1946 A U.S. Air Force study concluded that titanium-based alloys were engineering materials of potentially great importance for jet aircraft [11]
  • 1947 The U.S. Bureau of Mines, under R.S. Dean’s direction, produced nearly 2 tons of titanium metal using a modified Kroll process [14]
  • 1948 DuPont Company began industrial production of titanium sponge using the magnesium reduction method, producing 2 tons and marking the beginning of industrial titanium production [1, 2, 3, 13]
  • 1950 The U.S. Department of Defense provided production incentives to start the titanium industry; the Soviet Union pioneered titanium use in military and submarine applications; titanium came into extensive use in military aviation, particularly in high-performance jets like the F-100 Super Sabre; the United States developed the first titanium alloy (Ti-13V-11Cr-3Al) for flight applications; titanium alloys developed rapidly in the aerospace industry; the Orenda Iroquois jet engine used titanium components [4, 11, 16, 18, 20, 26]
  • 1953 Annual titanium production reached 2 million pounds (907,200 kg) with the U.S. military as primary customer [14]
  • 1956 Global titanium production reached 25,000 tons per year [13]
  • 1958 Demand for titanium dropped significantly as the military shifted focus from manned aircraft to missiles [14]
  • 1965 Per-Ingvar BrÃ¥nemark discovered osseointegration when titanium cameras integrated perfectly with rabbit bone tissue [25]
  • 1972 The FAA mandated a switch from Argon Remelting to double vacuum arc remelting for aerospace titanium [7]
  • 1973 The OPEC oil crisis increased titanium adoption in aerospace due to fuel efficiency needs [7]
  • 1979 The first total hip replacement surgery using titanium alloy implants was performed [1]
  • 1980 Triple melt VAR became the minimum standard for aerospace titanium [7]
  • 1981 Hideo Kodama laid the foundation for additive manufacturing technology that would later be applied to titanium 3D printing [27]
  • 1982 BrÃ¥nemark presented his research on osseointegrated titanium implants in Toronto, Canada, achieving 97% success rate [25]
  • 1984 Charles Hull patented stereolithography, foundational technology for 3D printing metals including titanium [27]
  • 1987 3D Systems introduced commercial additive manufacturing with stereolithography, later adapted for titanium powder processing; Michael Suisman warned of “titanium disease” – an obsession with the metal’s properties in industry [17, 30]
  • 1989 The Sioux City air disaster occurred when a titanium engine bore cracked, leading to industry-wide improvements in titanium quality control; Scott Crump filed patent for Fused Deposition Modeling, later adapted for titanium metal printing [7, 27]
  • 1990 Major technological advances in 3D printing expanded capabilities for titanium powder processing; early efforts at metal injection molding (MIM) of titanium with nonstructural parts began [27, 33]
  • 1991 Titanium tetrachloride complexes tested for cancer treatment applications [34]
  • 1992 Japan developed titanium-based golf club heads for commercial market [10]
  • 1993 Beta titanium alloys Ti-3Al-8V-6Cr-4Mo-4Zr and β-CEZ developed for aerospace applications [32]
  • 1994 Materials Properties Handbook: Titanium Alloys published by ASM International [32]
  • 1995 Titanium hip replacement systems achieved 10-year survival rates exceeding 95% [23]
  • 1996 Schutz reported on development of titanium alloy environmental behavior at 8th World Conference [32]
  • 1997 Ti-15Zr-4Nb-4Ta alloy developed for medical applications with improved biocompatibility [22]
  • 1998 Titanium sponge plant established in Kerala, India by KMML [15]
  • 1999 Polish company Zaklady Chemiczne produced 36,000 tons/year rutile pigment using sulfate technology [28]
  • 2000 The U.S. Defense National Stockpile Center dispersed its titanium sponge stockpile maintained since the Cold War; spray deposition of titanium attempted [4, 33]
  • 2001 The first artificial heart with titanium components was implanted in a human [1, 14]
  • 2002 Titanium hip implants demonstrated 98% success rate in 10-year follow-up studies [21]
  • 2003 Commercial 3D printers became more affordable for titanium powder processing [30]
  • 2004 Titanium foam structures developed for improved osseointegration in medical implants [24]
  • 2005 Electron beam melting technology commercialized for titanium additive manufacturing [30]
  • 2006 Boeing’s 777 aircraft utilized 59 metric tonnes of titanium in its construction; VSMPO-AVISMA supplied titanium for Boeing through strategic partnership [13, 32]
  • 2007 China’s titanium ingot capacity exceeded 50,000 metric tons annually [36]
  • 2008 Global financial crisis caused significant reduction in titanium output worldwide [36]
  • 2009 Recovery in titanium activity began following 2008 economic downturn [36]
  • 2010 Titanium alloy Ti-5553 (Ti-5Al-5V-5Mo-3Cr) developed for aerospace landing gear applications [29]
  • 2011 RTi International, a titanium manufacturer, acquired Aeromet International to expand titanium aerospace component production; China’s titanium consumption increased by 30% from previous year [36, 37]
  • 2012 China’s titanium ingot output reached highest level; 12 titanium sponge manufacturers shut down in China since this year [36]
  • 2013 RTi International, a titanium manufacturer, acquired Osborne Steel Extrusions to expand titanium processing capabilities; titanium 3D printing achieved 0.25mm layer resolution [31, 36]
  • 2014 Alcoa acquired Firth Rixson, expanding aerospace titanium component manufacturing capabilities; paradigm shift in chemical process industry toward titanium for corrosion resistance [35, 36]
  • 2015 Indian Space Research Organisation’s titanium sponge plant in Kerala was fully commissioned; RTi International (titanium manufacturer) acquired by Alcoa; electrochemical conditioning identified as major cost reduction opportunity for titanium processing [10, 36, 41]
  • 2016 Novel bioactive titanium materials developed using simulated body fluid evaluation [38]
  • 2017 Titanium implants with elastic modulus matching human bone achieved through new Ti-Nb-Ta-Zr alloy development; global aerospace additive manufacturing market (including titanium) valued at $0.9 billion [38, 40]
  • 2018 Titanium alloy TNM (Ti-43.5Al-4Nb-1Mo-0.1B) forgings qualified for aerospace applications [41]
  • 2019 ICME framework validated for predicting location-specific fatigue properties in titanium [41]
  • 2020 COVID-19 pandemic increased demand for titanium in medical equipment and implants; China produced 1922 tons of gadolinium with applications in titanium alloys [37, 40]
  • 2021 China produced 52% of global titanium sponge, followed by Japan (24%), Russia (16%), and Kazakhstan (7%) [4]
  • 2022 The global titanium market was valued at approximately $28 billion; LB Group announced $157.6 million investment in 200,000 ton/year TiO2 plant [19, 28]
  • 2023 Global mine production of titanium minerals reached an estimated 9.2 million metric tons; Titanium Industries enhanced processing capabilities for 50th anniversary [12, 39]
  • 2024 Titanium additive manufacturing achieved production status for structural aerospace components [41]
  • 2025 Airbus A380 utilizes 145 tonnes of titanium alloy Ti-6Al-4V in its construction [1]
  • 2030 The titanium market is projected to reach $52 billion [12, 19]

Final Thoughts

As we stand at the threshold of new technological frontiers, titanium continues to demonstrate why it earned its mythological name. From its humble discovery in Cornish beach sands to its current role in spacecraft, medical implants, and additive manufacturing, titanium has proven itself indispensable to human progress. The metal’s unique combination of strength, lightness, and biocompatibility positions it at the center of emerging technologies, from 3D-printed aerospace components to next-generation medical devices.

While challenges remain in reducing production costs and environmental impact, ongoing innovations in processing techniques and recycling promise to make titanium even more accessible. As humanity reaches toward the stars and seeks to enhance quality of life on Earth, titanium will undoubtedly continue to play a crucial role in shaping our technological future, truly living up to its titanic legacy.

Thanks for reading!

References

[1] Early discoveries about titanium – timeline – https://www.sciencelearn.org.nz/resources/1817-early-discoveries-about-titanium-timeline

[2] When Titanium Was Discovered – https://www.samaterials.com/content/when-titanium-was-discovered.html

[3] A Brief History of Titanium | Refractory Metals and Alloys – https://www.refractorymetal.org/a-brief-history-of-titanium.html

[4] Titanium – Wikipedia – https://en.wikipedia.org/wiki/Titanium

[5] How was titanium discovered? | History of Titanium – SAM Sputter Targets – http://www.sputtering-targets.net/blog/how-was-titanium-discovered-history-of-titanium/

[6] WebElements Periodic Table » Titanium » historical information – https://winter.group.shef.ac.uk/webelements/titanium/history.html

[7] History of Titanium – Kyocera SGS Europe – https://kyocera-sgstool.co.uk/titanium-resources/titanium-information-everything-you-need-to-know/history-of-titanium/

[8] Facts About Titanium | Live Science – https://www.livescience.com/29103-titanium.html

[9] The history of titanium: from discovery to modern use – Keith Titanium – https://keitheurope.com/en/blogs/our-indoor-blog/the-history-of-titanium-from-discovery-to-modern-use

[10] Timeline of titanium – Timelines – https://timelines.issarice.com/wiki/Timeline_of_titanium

[11] Titanium processing | Technology, Methods, & Facts | Britannica – https://www.britannica.com/technology/titanium-processing

[12] Global titanium production by country 2023 | Statista – https://www.statista.com/statistics/759972/mine-production-titanium-minerals-worldwide-by-country/

[13] Titanium (Ti) – a brief history of the origins and commercial applications of titanium | Double Stone Steel – https://www.doublestonesteel.com/blog/metal-blog/titanium-ti-part-of-a-series-on-metals-commonly-alloyed-with-stainless-steel-to-form-varying-grades-of-material/

[14] How titanium is made – material, manufacture, making, history, used, processing, parts, components, composition – https://www.madehow.com/Volume-7/Titanium.html

[15] Titanium production by country – Wikipedia – https://en.wikipedia.org/wiki/Titanium_production_by_country

[16] A Brief History of Titanium and Titanium Alloys – http://www.metalspiping.com/a-brief-history-of-titanium-and-titanium-alloys.html

[17] Titanium: A Fascinating History and Future – Solar Atmospheres – https://solaratm.com/tech-downloads/titanium-a-fascinating-history-and-future/

[18] Titanium Used in the Aerospace Industry – https://www.samaterials.com/content/which-titanium-is-used-in-aircrafts.html

[19] Titanium in Aerospace: Advantages, Applications, and Manufacturing – https://www.thomasnet.com/insights/titanium-in-aerospace/

[20] Unlocking Titanium Alloys in Aerospace – https://www.numberanalytics.com/blog/ultimate-guide-titanium-alloys-aerospace

[21] Titanium for Orthopedic Applications: An Overview of Surface Modification to Improve Biocompatibility and Prevent Bacterial Biofilm Formation – PMC – https://pmc.ncbi.nlm.nih.gov/articles/PMC7670191/

[22] Frontiers | Titanium–Tissue Interface Reaction and Its Control With Surface Treatment – https://www.frontiersin.org/journals/bioengineering-and-biotechnology/articles/10.3389/fbioe.2019.00170/full

[23] History of titanium application to medicine and development of titanium… | Download Scientific Diagram – https://www.researchgate.net/figure/History-of-titanium-application-to-medicine-and-development-of-titanium-alloys_tbl1_334519553

[24] Biomedical Applications of Titanium Alloys: A Comprehensive Review – PMC – https://pmc.ncbi.nlm.nih.gov/articles/PMC10780041/

[25] Titanium in Dentistry: Historical Development, State of the Art and Future Perspectives – PMC – https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3634937/

[26] Perspective Chapter: Titanium – A Versatile Metal in Modern Applications | IntechOpen – https://www.intechopen.com/chapters/1179178

[27] 3D Printing History: A Complete Timeline of Additive Manufacturing Technologies – Raise3D: Reliable, Industrial Grade 3D Printer – https://www.raise3d.com/blog/3d-printing-history/

[28] Processing of titanium-containing ores for the production of titanium products: A comprehensive review – PMC – https://pmc.ncbi.nlm.nih.gov/articles/PMC10847874/

[29] Modern Production Methods for Titanium Alloys: A Review | IntechOpen – https://www.intechopen.com/chapters/68769

[30] A review on various approaches of 3D printing of Ti-Alloy – ScienceDirect – https://www.sciencedirect.com/science/article/abs/pii/S2214785322026967

[31] How, When, Why: A Guide to 3D Printing with Titanium – 3DPrint.com | The Voice of 3D Printing / Additive Manufacturing – https://3dprint.com/111142/3d-printing-with-titanium/

[32] Titanium Alloys: Part 2—Alloy Development, Properties and Applications | SpringerLink – https://link.springer.com/chapter/10.1007/978-981-10-2134-3_6

[33] A historical perspective of titanium powder metallurgy – ScienceDirect – https://www.sciencedirect.com/science/article/abs/pii/B9780128000540000010

[34] Titanium – Wikipedia – https://en.wikipedia.org/wiki/Titanium

[35] TITANIUM 2010 – 2014 – International Titanium Association – https://titanium.org/general/custom.asp?page=ti_2010_2014

[36] The 13th World Conference on Titanium (Ti-2015) | JOM – https://link.springer.com/article/10.1007/s11837-016-2045-4

[37] Uncovering spatiotemporal evolution of titanium in China: A dynamic material flow analysis – ScienceDirect – https://www.sciencedirect.com/science/article/abs/pii/S0921344922000143

[38] A state-of-the-art review of the fabrication and characteristics of titanium and its alloys for biomedical applications | Bio-Design and Manufacturing – https://link.springer.com/article/10.1007/s42242-021-00170-3

[39] Titanium Industries 2023 Recap: Improved Productivity & Enhanced Processing Capabilities – Titanium Industries, Inc. – https://titanium.com/2023-recap-improved-productivity-enhanced-processing-capabilities

[40] A state-of-the-art review of the fabrication and characteristics of titanium and its alloys for biomedical applications – PMC – https://pmc.ncbi.nlm.nih.gov/articles/PMC8546395/

[41] (PDF) RECENT ADVANCES IN TITANIUM TECHNOLOGY IN THE UNITED STATES – https://www.researchgate.net/publication/346189371_RECENT_ADVANCES_IN_TITANIUM_TECHNOLOGY_IN_THE_UNITED_STATES